{UTF-8} ******************************************************** .Typ 10 Autokatalyse ********************************************************~ Simulation: Peter Bützer | RG1= IF THEN ELSE(E1<=0, 0 , GG ) ~ ~ | E= INTEG ( -GG, 0.1) ~ ~ Oxalsäure | E1= INTEG ( -RG1, 0.01) ~ ~ Kalumpermanganat wird gleich rasch umgewandelt, wie die Oxalsäure. Dabei \ bildet sich aber der Katalysator Mn2+ | EKat= INTEG ( GG-RG, 0) ~ ~ Substrat-Enzym-Komplex | GG= k1*E*Kfrei-k2*EKat ~ ~ Gleichgewichtsreaktion | K= 100 ~ [10,1000,10] ~ Gleichgewichtskonstante | k1= 0.1 ~ [0.1,2] ~ Reaktions-Geschwindikgeits-Konstante der Vorwärtsreaktion | k2= k1/K ~ ~ Reaktions-Geschwindigkeits-Konstante der Rückreaktion | k3= 1 ~ [0,5] ~ Reaktions-Geschwindigkeitskonstante der Produktebildung | Kat= INTEG ( RG1, 0.001) ~ ~ Mn2+ als Katalysator | Kfrei= Kat-EKat ~ ~ | P= INTEG ( RG, 0) ~ ~ Produkt | RG= k3*EKat ~ ~ | ******************************************************** .Control ********************************************************~ Simulation Control Parameters | FINAL TIME = 500 ~ Second ~ The final time for the simulation. | INITIAL TIME = 0 ~ Second ~ The initial time for the simulation. | SAVEPER = 1 ~ Second [0,?] ~ The frequency with which output is stored. | TIME STEP = 0.1 ~ Second [0,?] ~ The time step for the simulation. | \\\---/// Sketch information - do not modify anything except names V300 Do not put anything below this section - it will be ignored *View 1 $192-192-192,0,Times New Roman|12||0-0-0|0-0-0|0-0-255|-1--1--1|-1--1--1|120,120,100,0 10,1,EKat,509,278,66,33,3,3,0,0,0,0,0,0 10,2,P,804,284,66,33,3,3,0,4,0,0,0,0,0-0-0,0-255-255,|12||0-0-0 1,3,5,2,4,0,0,22,0,0,0,-1--1--1,,1|(701,280)| 1,4,5,1,100,0,0,22,0,0,0,-1--1--1,,1|(610,280)| 11,5,348,656,280,10,14,34,3,0,0,1,0,0,0 10,6,RG,656,311,21,18,40,3,0,0,-1,0,0,0 1,7,1,5,1,0,0,0,0,64,0,-1--1--1,,1|(615,215)| 10,8,E1,236,471,66,33,3,3,0,4,0,0,0,0,0-0-0,255-0-255,|12||0-0-0 10,9,Kat,510,471,66,33,3,3,0,4,0,0,0,0,0-0-0,192-192-192,|12||0-0-0 1,10,12,9,4,0,0,22,0,0,0,-1--1--1,,1|(406,469)| 1,11,12,8,100,0,0,22,0,0,0,-1--1--1,,1|(325,469)| 11,12,332,359,469,10,14,34,3,0,0,1,0,0,0 10,13,RG1,359,500,28,18,40,3,0,0,-1,0,0,0 10,14,E,240,274,66,33,3,3,0,4,0,0,0,0,0-0-0,192-255-255,|12||0-0-0 1,15,17,1,4,0,0,22,0,0,0,-1--1--1,,1|(413,276)| 1,16,17,14,100,0,0,22,0,0,0,-1--1--1,,1|(335,276)| 11,17,204,374,276,10,14,34,3,0,0,1,0,0,0 10,18,GG,374,306,21,18,40,3,0,0,-1,0,0,0 1,19,14,17,1,0,0,0,0,64,0,-1--1--1,,1|(316,205)| 1,20,1,18,1,0,0,0,0,64,0,-1--1--1,,1|(456,356)| 10,21,Kfrei,363,389,30,18,8,3,0,0,0,0,0,0 1,22,9,21,1,0,0,0,0,64,0,-1--1--1,,1|(398,430)| 1,23,1,21,1,0,0,0,0,64,0,-1--1--1,,1|(471,378)| 1,24,21,17,1,0,0,0,0,64,0,-1--1--1,,1|(338,350)| 10,25,k1,259,138,16,18,8,3,0,0,0,0,0,0 10,26,k2,173,355,16,18,8,3,0,0,0,0,0,0 10,27,K,94,385,14,18,8,3,0,0,0,0,0,0 1,28,25,17,1,0,0,0,0,64,0,-1--1--1,,1|(356,180)| 1,29,26,17,1,0,0,0,0,64,0,-1--1--1,,1|(265,334)| 1,30,25,26,1,0,0,0,0,64,0,-1--1--1,,1|(120,266)| 1,31,27,26,1,0,0,0,0,64,0,-1--1--1,,1|(149,373)| 10,32,k3,561,143,16,18,8,3,0,0,0,0,0,0 1,33,32,5,1,0,0,0,0,64,0,-1--1--1,,1|(645,175)| 1,34,17,12,1,0,0,0,0,64,0,-1--1--1,,1|(315,378)| 1,35,8,12,1,0,0,0,0,64,0,-1--1--1,,1|(294,539)| ///---\\\ :L<%^E!@ 9:Current 23:0 15:0,0,0,0,0,0 19:100,0 27:2, 34:0, 5:E 24:0 25:0 26:0